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An aqueous solution has a normal boiling point of 103.0 °C. What is the freezing point of this solution? For water Kb = 0.51 °C m-1 and Kf = 1.86 °C m-1.


A) -0.82 °C
B) -3.0 °C
C) -3.6 °C
D) -11 °C

E) B) and C)
F) A) and C)

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A solution containing less than the equilibrium amount is called


A) an unsaturated solution.
B) a dilute solution.
C) a supersaturated solution.
D) a concentrated solution.
E) a saturated solution.

F) All of the above
G) D) and E)

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How many moles of KF are contained in 347 g of water in a 0.175 mol kg-1 KF solution?


A) 1.65 × 10-2 mol KF
B) 5.04 × 10-2 mol KF
C) 6.07 × 10-2 mol KF
D) 3.22 × 10-2 mol KF
E) 1.98 × 10-2 mol KF

F) None of the above
G) All of the above

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A solution is prepared by adding 1.43 mol of KCl to 889 g of water. The concentration of KCl is ________ molal.


A) 1.61 × 10-3
B) 622
C) 0.622
D) 1.27 × 103
E) 1.61

F) C) and D)
G) A) and B)

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Calculate the vapour pressure of pure water at 85 °C if a 285 mL solution containing 173.0 g of mannose, C6H12O6, has a vapour pressure of 545.0 mbar.


A) 531 mbar
B) 578 mbar
C) 508 mbar
D) 599 mbar
E) 520 mbar

F) C) and D)
G) A) and D)

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Which of the following statements is TRUE?


A) In general, the solubility of a solid in water decreases with increasing temperature.
B) In general, the solubility of a gas in water decreases with increasing temperature.
C) The solubility of a gas in water usually increases with decreasing pressure.
D) The solubility of an ionic solid in water decreases with increasing temperature.
E) None of the above statements is true.

F) A) and B)
G) B) and C)

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What is the term for the amount of solute in moles per litre of solution?


A) molality
B) molarity
C) mole fraction
D) mole percent
E) mass percent

F) A) and E)
G) A) and D)

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Which cation in each set is expected to have the larger (more negative) hydration energy? I Be2+ or Ca2+ II Rb+ or Zn2+


A) Be2+ in set I and Rb+ in set II
B) Be2+ in set I and Zn2+ in set II
C) Ca2+ in set I and Rb+ in set II
D) Ca2+ in set I and Zn2+ in set II

E) B) and C)
F) B) and D)

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A 1.00 L sample of water contains 0.0036 g of Cl⁻ ions. Determine the concentration of chloride ions in ppm if the density of the solution is 1.00 g mL-1.


A) 2.8 ppm
B) 7.2 ppm
C) 3.6 ppm
D) 1.8 ppm
E) 5.4 ppm

F) A) and D)
G) C) and D)

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Which of the following compounds will be most soluble in ethanol (CH3CH2OH) ?


A) trimethylamine (N(CH3) 3)
B) acetone (CH3COCH3)
C) ethylene glycol (HOCH2CH2OH)
D) hexane (CH3CH2CH2CH2CH2CH3)
E) None of these compounds should be soluble in ethanol.

F) A) and D)
G) All of the above

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Define the Tyndall effect.

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The Tyndall effect i...

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How much water must be added to 40.0 g of CaCl2 to produce a solution that is 35.0 wt% CaCl2?


A) 54.0 g
B) 74.2 g
C) 87.5 g
D) 114 g

E) All of the above
F) B) and D)

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Calculate the volume of solution that has a vapour pressure of 31.27 mbar and contains 84.3 g of sucrose, C12H22O11, at a temperature of 25.0 °C. The vapour pressure of pure water at 25 °C is 31.7 mbar, the density of water is 1.00 g mL-1, and assume no change in volume occurs upon dissolution.


A) 204 mL
B) 31.8 mL
C) 286 mL
D) 323 mL
E) 516 mL

F) B) and C)
G) A) and E)

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Calculate the total solution volume required to produce an osmotic pressure of 6.39 mbar using 12.34 mg of a protein with a molar mass of 5309 g mol-1 at 25.0 °C.


A) 12.5 mL
B) 11.8 mL
C) 9.91 mL
D) 8.37 mL
E) 9.02 mL

F) None of the above
G) C) and E)

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What mass of ethane (CH3CH3) is contained in 50.0 mL of a 13.9% by mass solution of ethane in hexane? The density of the solution is 0.611 g mL-1.


A) 2.35 g
B) 8.49 g
C) 11.8 g
D) 6.95 g
E) 4.25 g

F) None of the above
G) B) and E)

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How does a solution of two volatile components with strong solute-solvent attractions deviate from Raoult's law? Why?

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The vapour pressure of the solution will...

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Match the following. -0.050 mol kg-1 NaCl


A) largest van't Hoff factor
B) solution that is most strongly dependent upon pressure
C) solution of ionic compound with highest freezing point.
D) highest boiling point
E) solution with ΔTb = 0.026 °C

F) A) and B)
G) B) and D)

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A solution is prepared by dissolving 38.6 g sucrose (C12H22O11) in 495 g of water. Determine the mole fraction of sucrose if the final volume of the solution is 508 mL.


A) 4.09 × 10-3
B) 7.80 × 10-2
C) 1.28 × 10-3
D) 7.23 × 10-2
E) 2.45 × 10-3

F) C) and D)
G) A) and C)

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Calculate the solution temperature required to produce an osmotic pressure of 1.18 mbar using 3.72 mg of a protein with a molar mass of 4176 g mol-1 that is dissolved in enough water to create 20.9 mL of solution.


A) 333 K
B) 298 K
C) 316 K
D) 351 K
E) 288 K

F) B) and E)
G) None of the above

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